A Bio Geek's Aslyum

~ Monday, March 19 ~
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the-star-stuff:

How Much Water is On Earth?

In this illustration, the blue ball represents the volume of all the water on earth, relative to the size of the earth. The tiny speck to the right of the blue ball represents Earth’s fresh water. CREDIT: David Gallo/WHOI 

If Earth was the size of a basketball, all of its water would fit into a ping pong ball.
How much water is that? It’s roughly 326 million cubic miles (1.332 billion cubic kilometers), according to a recent study from the U.S. Geological Survey. Some 72 percent of Earth is covered in water, but 97 percent of that is salty ocean water and not suitable for drinking.
“There’s not a lot of water on Earth at all,” said David Gallo, an oceanographer at the Woods Hole Oceanographic Institution (WHOI) in Massachusetts.

the-star-stuff:

How Much Water is On Earth?

In this illustration, the blue ball represents the volume of all the water on earth, relative to the size of the earth. The tiny speck to the right of the blue ball represents Earth’s fresh water. CREDIT: David Gallo/WHOI 

If Earth was the size of a basketball, all of its water would fit into a ping pong ball.

How much water is that? It’s roughly 326 million cubic miles (1.332 billion cubic kilometers), according to a recent study from the U.S. Geological Survey. Some 72 percent of Earth is covered in water, but 97 percent of that is salty ocean water and not suitable for drinking.

“There’s not a lot of water on Earth at all,” said David Gallo, an oceanographer at the Woods Hole Oceanographic Institution (WHOI) in Massachusetts.


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~ Monday, February 20 ~
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doktorengine:

/dead

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~ Monday, February 13 ~
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~ Friday, February 3 ~
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~ Saturday, January 21 ~
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incidentalcomics:

The Ellipse

incidentalcomics:

The Ellipse


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~ Thursday, January 19 ~
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Sodium, sodium, sodium, sodium, sodium, sodium, sodium, sodium, BATMAN!

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How to Calculate Degrees of Unsaturation without Formula

Everywhere I looked, resources kept giving me a formula of how to determine units/degrees of unsaturation for a chemical structure, but they didn’t tell me the reasoning behind the formula, or how to find it with just the structure.

Until today!

http://www.goiit.com/posts/list/community-shelf-degree-of-unsaturation-925585.htm;jsessionid=EB936512FD7CEE87EAB835AC20FED84B.node2#989115

All alkanes have the exact same empirical formula. Specifically, for every carbon in an alkane there will be twice as many hydrogens plus two, and so every alkane has the formula CnH2n+2, where n represents the number of carbons. Alkanes are said to be hydrogen saturated since they have the maximum number of hydrogens possible. Hydrocarbons that contain a single alkene (carbon-carbon double bond) or contain a single ring are said to contain a single degree of unsaturation because adding either a ring or a double bond requires loss of two hydrogens, and so these molecules have the formula CnH2n. Hydrocarbons that contain two double bonds, 2 rings, or an alkyne (a triple bond) are said to contain two degrees of unsaturation and have the formula CnH2n-2, representing a loss of an additional two hydrogens. 


Determining degrees of unsaturation from a formula
A general formula for calculating the degrees of unsaturation from a molecular formula is the following:
Degrees of Unsaturation = [(Number of Carbons x 2) + 2 - Number of Hydrogens] / 2
 
For non hydrocarbon elements:
Oxygen—ignore
Halides (F, Cl, Br, I)—count as a hydrogen
Nitrogen—count as one half of a carbon
Determining degrees of unsaturation from a structure
Determining the degrees of unsaturation from a structure rather than a formula is easy:
  • Double bonds add one degree of unsaturation
  • Rings add one degree of unsaturation
  • Triple bonds add two degrees of unsaturation
 
 
 
The total unsaturation in a molecule is the sum of each of the molecules elements of unsaturation. For example, a hydrocarbon containing a ring and an alkyne is said to have three degrees of unsaturation (one for the ring and two for the triple bond).
Knowing the degrees of unsaturation in a molecule is quite useful when trying to determine a structure, because it tells whether double or triple bonds or rings are present, and how many (although it doesn’t tell you which ones are present.

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~ Tuesday, January 17 ~
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I am devastated to say that I tried planting a Chinese Forget-me-not in my dorm room and I think the cold from the window has frozen it to death…

I am devastated to say that I tried planting a Chinese Forget-me-not in my dorm room and I think the cold from the window has frozen it to death…


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Orbital Hybridization

When I took AP Chemistry in high school, we basically completely skipped over hybridization.  Apparently it was too difficult and unnecessary.  We learned the basic structures for various molecular structures, i.e. tetrahedral, trigonal planar, etc.  The faculty here at University of Michigan were surprised to hear that we had no experience with it…  

My organic chemistry book “Organic Chemistry: Structure and Reactivity, 5th ed.” by Seyhan has the most lengthy and confusing explanation for hybridization I have ever read.  I almost wish I had my AP Chemistry textbook with me.  I consented to Google.  Be warned - a proper understanding of pi and sigma bonds are needed before jumping into this.

Basic Explanationhttp://www.grandinetti.org/comment/18

Animationhttp://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/hybrv18.swf

Normally, I’d be fairly satisfied with this, but they failed to explain the exact details of why and specifically how hybridization works.  They didn’t talk about nodes (a region where the probability of finding an electron is zero, according to Seyhan), nor did they talk about ethers, esters, alkenes, and all those other molecular structures and how they relate to orbital hybridization.  Well, back to the book!


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